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<div id="qwcagsgoaso" class="text-more" contextmenu="return false" unselectable="on">  <div> <p>1910-1911年，前蘇聯(lián)用堿金屬引發(fā)丁二烯聚合得到橡膠狀物質(zhì)。20世紀30年代初，德國和前蘇聯(lián)開(kāi)始生產(chǎn)以金屬鈉為催化劑的丁二烯橡膠，稱(chēng)為丁鈉橡膠，其結構規整性差，物性和加工性能不好，還不能算做順丁橡膠。20世紀50年代，Ziegler-Natta配位定向聚合理論的實(shí)踐，促進(jìn)了順丁橡膠合成技術(shù)的迅速發(fā)展。1956年，美國以AlR3-TiBr4催化體系合成順丁橡膠。隨后鈷系、鎳系及稀土系（釹系）催化劑相續發(fā)展，順丁橡膠生產(chǎn)能力已僅次于丁苯橡膠，合成橡膠各膠種第二位。2013年世界合成橡膠生產(chǎn)者協(xié)會(huì )統計丁二烯橡膠（主要為順丁橡膠）產(chǎn)能為471.8萬(wàn)噸/年。<br /> 我國在上世紀70年代采用自主開(kāi)發(fā)的技術(shù)實(shí)現了順丁橡膠工業(yè)化生產(chǎn)，采用的是鎳系催化劑，其生產(chǎn)技術(shù)一直處于世界水平行列。中國石化、中國石油和一些民企均擁有鎳系順丁橡膠生產(chǎn)裝置，2011年總產(chǎn)能達66萬(wàn)噸/年，產(chǎn)品銷(xiāo)往。未來(lái)幾年，我國鎳系順丁橡膠產(chǎn)能將進(jìn)一步擴大，預計我國鎳系順丁橡膠產(chǎn)能將超過(guò)100萬(wàn)噸/年。 <br /> 稀土順丁橡膠因其的性能被視為鎳系順丁橡膠的升級品種，逐漸被工業(yè)界所重視。稀土順丁橡膠與鎳系順丁橡膠相比具有較高的彈性、較好的拉伸性能、較低的生熱和滾動(dòng)阻力以及的耐磨耗和抗疲勞等物理機械性能，符合輪胎在高速、節能、安全、環(huán)保等方面發(fā)展的需要，常用于綠色輪胎。中國早在上世紀60年代就開(kāi)始了稀土催化丁二烯聚合的研究，由于當時(shí)經(jīng)濟發(fā)展落后，未能實(shí)現工業(yè)化生產(chǎn)。1998年在國家863計劃的支持下，中國石油錦州石化公司在鎳系萬(wàn)噸級順丁橡膠生產(chǎn)裝置上成功地生產(chǎn)出了稀土順丁橡膠。2011年，中國石油山子石化公司稀土順丁橡膠生產(chǎn)裝置投產(chǎn)，中國稀土順丁橡膠生產(chǎn)裝置實(shí)現了零突破。2012年，中國石化北京燕山分公司3萬(wàn)噸/年稀土順丁橡膠生產(chǎn)裝置也投產(chǎn)。未來(lái)幾年，我國將新增20多萬(wàn)噸/年稀土順丁橡膠的產(chǎn)能，屆時(shí)中國稀土順丁橡膠總產(chǎn)能達30萬(wàn)噸/年以上，成為稀土順丁橡膠大生產(chǎn)大國。<br/><img src="http://jmage0.huangye88.net/live/2022/04/18/d6ebfe00c45a35225899f829d0e716c3.jpg@750w_750h_90Q" /><br/>色母是20世紀60年代開(kāi)發(fā)的一種塑料、纖維的著(zhù)色新產(chǎn)品，它是把顏料超常量均勻的載附于樹(shù)脂中而制得的聚合物的復合物。色母主要組成為著(zhù)色劑、載體、分散劑三部分。<br /> 據相關(guān)資料獲悉，亞洲地區的其他國家對色母的年均需求增長(cháng)率約7%－9%，可我國對色母的年均需求增長(cháng)率為20%左右。預計中國將成為色母需求量增長(cháng)快的市場(chǎng)。特別是彩色和添加母粒，我國要依賴(lài)進(jìn)口。我國已成了亞洲地區色母市場(chǎng)的大生產(chǎn)國和消耗國。我國有330家生產(chǎn)色母的企業(yè)，其中塑料級色母廠(chǎng)已經(jīng)達到了 300家，纖維級色母廠(chǎng)為30家，這些色母生產(chǎn)廠(chǎng)主要分布在福建、廣東、山東、浙江、江蘇、上海、遼寧、天津、北京、河北等省市。我國色母粒年生產(chǎn)能力在1000噸以上的企業(yè)有將近50家，全國色母生產(chǎn)能力為每年30萬(wàn)噸，2001年我國色母的需求量不到12萬(wàn)噸。生產(chǎn)能力嚴重過(guò)剩，導致國內色母行業(yè)普遍開(kāi)工不足，除新建生產(chǎn)裝置增速過(guò)快，產(chǎn)品訂單不足等因素外；其中重要因素是國產(chǎn)色母產(chǎn)品結構單一，品種不全，通用型產(chǎn)品占很大比重，而高濃度和濃度、多功能性色母及細旦纖維用色母所占比重較少。反觀(guān)色母技術(shù)水平較高的國家，顏料、分散劑等原材料品種，已形成了系列化和化產(chǎn)品結構。在品種開(kāi)發(fā)方面，我國色母生產(chǎn)廠(chǎng)家已經(jīng)開(kāi)發(fā)出了纖維用色母、薄膜用色母、電線(xiàn)電纜用色母、聚烯烴色母、PVC色母、注塑制品用色母。有關(guān)認為，未來(lái)色母將朝著(zhù)多功能化、高顏色含量和高技術(shù)含量方向發(fā)展，色母的發(fā)展伴隨著(zhù)對生產(chǎn)技術(shù)的提高。<br/><img src="http://jmage0.huangye88.net/live/2022/04/19/62c4e820801f76414e36d91b9b2219ae.jpg@750w_750h_90Q" /><br/>用途一：用作白色顏料、白色玻璃、搪瓷、藥物、膠合水泥、填充劑、媒染劑及防火涂料等<br /> 用途二：作為阻燃劑廣泛用于塑料、橡膠、紡織、化纖、顏料、油漆、電子等行業(yè)，也用作化工行業(yè)的催化劑和生產(chǎn)原料<br /> 用途三：用作高純試劑、媒染劑及防光劑，也用于顏料及酒石酸銻鉀的制備<br /> 用途四：用作各種樹(shù)脂、合成橡膠、帆布、紙張、涂料等的阻燃劑，石油化工、合成纖維的催化劑。用于制造媒染劑、乳白劑，是合成銻鹽的原料。搪瓷工業(yè)用作添加劑，以增加琺瑯的不透明性和表面光澤。玻璃工業(yè)用作代替亞砷酸的脫色劑。醫藥、冶金、軍工等。<br /> 用途五：優(yōu)良的無(wú)機白色顏料，主要用于油漆的著(zhù)色。用于各種樹(shù)脂、合成橡膠、帆布、紙張、涂料等的阻燃劑，石油化工、合成纖維的催化劑。用于制造媒染劑、乳白劑，是合成銻鹽的原料。搪瓷工業(yè)用作增加琺瑯的不透明性和表面光澤。玻璃工業(yè)用作代替亞砷酸的脫色劑。<br /> 用途六：三氧化二銻是一種良好的遮蓋劑，用作白色油漆顏料。用作各種樹(shù)脂、合成橡膠帆布、紙張、涂料等的阻燃劑，石油化工、合成纖維的催化劑。用于制造媒染劑、乳白劑，用于制白色玻璃、搪瓷、吐酒石、藥物、膠合水泥，也是合成銻鹽的原料，搪瓷工業(yè)添加劑，以增加琺瑯的不透明性和表面光澤。玻璃工業(yè)用作代替亞砷酸的脫色劑等<br/><img src="http://jmage0.huangye88.net/live/2022/04/19/1ce17409f4e1dcdd8b07d164d2857659.jpg@750w_750h_90Q" /><br/>食品原料在種植、收割、晾曬再到后的加工過(guò)程中會(huì )接觸到土壤或地面的礦物油、柴油、發(fā)動(dòng)機的潤滑油、沒(méi)有完全燃燒的汽油以及被污染的空氣等，這些因素都會(huì )使食品受到礦物油的污染。具體的污染來(lái)源主要有以下六大方面： <br /> 土壤或地面污染<br /> 國內部分地區的土壤污染較為嚴重，如果土壤被礦物油污染并且超過(guò)了一定時(shí)，就會(huì )被食品原料中的某些成分所吸收，從而富集在植物體內。并且收割的植物在晾曬的過(guò)程中，也可能被地面上的瀝青和滴落在地面上的潤滑油等礦物油類(lèi)物質(zhì)所污染。被污染的原料存在的大問(wèn)題就是礦物油在原料中很難被去除掉，造成了礦物油在食品原料中發(fā)生逐步富集，通過(guò)各個(gè)食品的加工程序，制成的成品中含有大量礦物油。 <br /> 農藥或殺蟲(chóng)劑等物質(zhì)<br /> 在農作物的生長(cháng)過(guò)程中，農藥或殺蟲(chóng)劑等物質(zhì)中含有的礦物油會(huì )被植物體吸收并在植物體內進(jìn)行富集，從而造成農作物的污染，并且農作物中的礦物油污染在后續加工中會(huì )一直存在，終影響人體健康。<br/><img src="http://jmage0.huangye88.net/live/2022/04/19/021b0a962e475047b7a3f8b3fa409361.jpg@750w_750h_90Q" /><br/>硅油一般是無(wú)色（或淡黃色）、無(wú)味、、不易揮發(fā)的液體。硅油不溶于水、甲醇、乙二醇和2-乙氧基乙醇，可與苯、二甲醚、甲基乙基酮、四氯化碳或煤油互溶，稍溶于丙酮、二惡烷、乙醇和丁醇。它具有很小的蒸汽壓、較高的閃點(diǎn)和燃點(diǎn)、較低的凝固點(diǎn)。隨著(zhù)鏈段數n的不同，分子量增大，粘度也增高，固此硅油可有各種不同的粘度，從0.65厘沲直到上百萬(wàn)厘沲。如果要制得低粘度的硅油，可用酸性白土作為催化劑，并在180℃溫度下進(jìn)行調聚，或用硫酸作為催化劑，在低溫度下進(jìn)行調聚，生產(chǎn)高粘度硅油或粘稠物可用堿性催化劑。<br /> 硅油具有耐熱性、電絕緣性、耐候性、疏水性、生理惰性和較小的表面張力，此外還具有低的粘溫系數、較高的抗壓縮性、有的品種還具有耐輻射的性能。<br/><img src="http://jmage0.huangye88.net/live/2022/04/19/bd3b7ba3c0486f880f241d501ac0fc78.jpg@750w_750h_90Q" /><br/>改性聚氨酯皮革涂飾劑<br /> 具有聚氨酯及環(huán)氧樹(shù)脂二者的性能，粘結性及彈性均佳。用于電器材料、皮革制品、尼龍傳送帶、橡膠制品、木制品、金屬材料的蒙皮涂層，更適合于軟彈性制品、竹、藤、傳送帶、膠帶、皮帶、革制品、橡塑材料等。優(yōu)于國內現有的頂層涂料，特別是球、皮衣、皮箱等，達到國外同類(lèi)產(chǎn)品的水平。在防水及耐磨性能方面，優(yōu)于聚丙烯酸酯及其改性涂飾劑的性能?？墒巩a(chǎn)品美觀(guān)、滑爽、使用壽命延長(cháng)。<br /> 適用范圍<br /> 聚氨酯是由多異氰酸酯與多元基化合物作用而成的高分子化合物，由于在大分子間存在著(zhù)氨氫鍵，所以其聚合物具有很好的強度，耐磨、耐溶劑等性能，使得聚氨酯在、橡膠、涂料、粘合劑、合成纖維等領(lǐng)域中有著(zhù)廣泛的應用，尤其是作為涂飾劑應用在皮革上。<br /> 近年來(lái)，隨著(zhù)環(huán)境保護意識和措施的加強，水性聚氨皮革涂飾劑的研究和開(kāi)發(fā)得到高度重視，陽(yáng)離子水性聚氨酯涂飾劑以其特的性能得到國內外廣泛究。本文介紹的陽(yáng)離子水性聚氨酯底層涂飾劑，具有一定的填充性能，封底，即可和帶負電荷的革坯產(chǎn)生更好的粘合，又可與陰離子的頂層涂飾劑起強有力的聯(lián)結效應，使制革手感更柔軟、豐滿(mǎn)，進(jìn)一步提高皮革質(zhì)量。</p> </div> <div id="qwcagsgoaso" class="pages"> <span id="qwcagsgoaso" class="leftpage"><font>上一條 </font><a target="_blank" title="廣元半精煉石蠟回收大量回收">廣元半精煉石蠟回收大量回收</a></span> <span id="qwcagsgoaso" class="rightpage"><font> 下一條</font><a href="http://m.guizhouboda.com/sell/info-661b3qqradc3f9.html" target="_blank" title="大連熱熔膠回收上門(mén)回收">大連熱熔膠回收上門(mén)回收</a></span> </div> </div> </div> </div> </div> <div id="qwcagsgoaso" class="list"> <h2 class="titles" style="float:left;">二手塑料顆?；厥障嚓P(guān)信息</h2> <a class="r-more" rel="nofollow" target="_blank" style="float:right;margin-right:30px;">查看更多信息</a> <div id="qwcagsgoaso" 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