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class="attribute-value"><div>全國</div></td> </tr> </table> <div id="qwcagsgoaso" class="text-more" contextmenu="return false" unselectable="on">  <div> <p>1910-1911年，前蘇聯(lián)用堿金屬引發(fā)丁二烯聚合得到橡膠狀物質(zhì)。20世紀30年代初，德國和前蘇聯(lián)開(kāi)始生產(chǎn)以金屬鈉為催化劑的丁二烯橡膠，稱(chēng)為丁鈉橡膠，其結構規整性差，物性和加工性能不好，還不能算做順丁橡膠。20世紀50年代，Ziegler-Natta配位定向聚合理論的實(shí)踐，促進(jìn)了順丁橡膠合成技術(shù)的迅速發(fā)展。1956年，美國以AlR3-TiBr4催化體系合成順丁橡膠。隨后鈷系、鎳系及稀土系（釹系）催化劑相續發(fā)展，順丁橡膠生產(chǎn)能力已僅次于丁苯橡膠，合成橡膠各膠種第二位。2013年世界合成橡膠生產(chǎn)者協(xié)會(huì )統計丁二烯橡膠（主要為順丁橡膠）產(chǎn)能為471.8萬(wàn)噸/年。<br /> 我國在上世紀70年代采用自主開(kāi)發(fā)的技術(shù)實(shí)現了順丁橡膠工業(yè)化生產(chǎn)，采用的是鎳系催化劑，其生產(chǎn)技術(shù)一直處于世界水平行列。中國石化、中國石油和一些民企均擁有鎳系順丁橡膠生產(chǎn)裝置，2011年總產(chǎn)能達66萬(wàn)噸/年，產(chǎn)品銷(xiāo)往。未來(lái)幾年，我國鎳系順丁橡膠產(chǎn)能將進(jìn)一步擴大，預計我國鎳系順丁橡膠產(chǎn)能將超過(guò)100萬(wàn)噸/年。 <br /> 稀土順丁橡膠因其的性能被視為鎳系順丁橡膠的升級品種，逐漸被工業(yè)界所重視。稀土順丁橡膠與鎳系順丁橡膠相比具有較高的彈性、較好的拉伸性能、較低的生熱和滾動(dòng)阻力以及的耐磨耗和抗疲勞等物理機械性能，符合輪胎在高速、節能、安全、環(huán)保等方面發(fā)展的需要，常用于綠色輪胎。中國早在上世紀60年代就開(kāi)始了稀土催化丁二烯聚合的研究，由于當時(shí)經(jīng)濟發(fā)展落后，未能實(shí)現工業(yè)化生產(chǎn)。1998年在國家863計劃的支持下，中國石油錦州石化公司在鎳系萬(wàn)噸級順丁橡膠生產(chǎn)裝置上成功地生產(chǎn)出了稀土順丁橡膠。2011年，中國石油山子石化公司稀土順丁橡膠生產(chǎn)裝置投產(chǎn)，中國稀土順丁橡膠生產(chǎn)裝置實(shí)現了零突破。2012年，中國石化北京燕山分公司3萬(wàn)噸/年稀土順丁橡膠生產(chǎn)裝置也投產(chǎn)。未來(lái)幾年，我國將新增20多萬(wàn)噸/年稀土順丁橡膠的產(chǎn)能，屆時(shí)中國稀土順丁橡膠總產(chǎn)能達30萬(wàn)噸/年以上，成為稀土順丁橡膠大生產(chǎn)大國。<br/><img src="http://jmage0.huangye88.net/live/2022/04/18/4b9daa46101b455cfe10eb5a3740d651.jpg@750w_750h_90Q" /><br/>危險品一般都是化工行業(yè)的原料、中間體、產(chǎn)品，運輸的方法選擇主要是針對相關(guān)產(chǎn)品的物理化學(xué)性質(zhì)來(lái)選擇，如果是一個(gè)生產(chǎn)、貿易或者物流企業(yè)，需要運輸危險品，要有該產(chǎn)品的MSDS（材料數據安全表），產(chǎn)品分三態(tài)：固液氣，固態(tài)一般只有用欄板車(chē)運輸，氣態(tài)只有用壓力鋼瓶或者壓力罐儲裝，液態(tài)產(chǎn)品靈活運輸，由于它和溫度關(guān)系很大對它的運輸有如下選擇：粘度大的一般桶裝后欄板車(chē)運輸或者保溫加熱槽車(chē)運輸；粘度與水接近的、蒸汽壓小、無(wú)腐蝕的化學(xué)品用普通常壓罐車(chē)運輸；有腐蝕的產(chǎn)品可用不銹鋼槽車(chē)運輸。<br/><img src="http://jmage0.huangye88.net/live/2022/04/18/9f023cb1af276cc6a2982090fde71ba7.jpg@750w_750h_90Q" /><br/>偶聯(lián)劑早由美國聯(lián)合碳化物公司（UCC）為發(fā)展玻璃纖維增強塑料而開(kāi)發(fā)。早在40年代，當玻璃纖維用作有機樹(shù)脂的增強材料，制備廣泛使用的玻璃鋼時(shí)，發(fā)現當它們長(cháng)期置于潮氣中，其強度會(huì )因為樹(shù)脂與親水性的玻璃纖維脫粘而明顯下降，進(jìn)而不能得到耐水復合材料。鑒于含有官能團的有機硅材料是同時(shí)與二氧化硅（即玻璃纖維的主要成分）和樹(shù)脂有兩親關(guān)系的有機材料及無(wú)機材料的“雜交”體，試用它作為“粘合劑”或偶聯(lián)劑，來(lái)改善有機樹(shù)脂與無(wú)機表面的粘接，以達到改善聚合物性能的目的，就成為科技工作者的一大設想，并在實(shí)際應用中取得了較好的效果。因此自40年代初至60年代是偶聯(lián)劑產(chǎn)生和發(fā)展時(shí)期，并形成了代硅烷類(lèi)偶聯(lián)劑。工業(yè)上使用偶聯(lián)劑按照化學(xué)結構分類(lèi)可分為：硅烷類(lèi)，鈦酸酯類(lèi)，鋁酸酯類(lèi)，有機鉻洛合物，硼化物，磷酸酯，鋯酸酯，錫酸酯等。它們廣泛地應用在塑料橡膠等高分子材料領(lǐng)域之中。</p> </div> <div id="qwcagsgoaso" class="pages"> <span id="qwcagsgoaso" class="leftpage"><font>上一條 </font><a href="http://m.guizhouboda.com/ershouhuishou/88-c72hv6o7o6981b.html" target="_blank" title="遼寧包裝破損食品添加劑上門(mén)回收">遼寧包裝破損食品添加劑上門(mén)回收</a></span> <span id="qwcagsgoaso" class="rightpage"><font> 下一條</font><a href="http://m.guizhouboda.com/ershouhuishou/88-e727n9t70f274a.html" target="_blank" title="十堰庫存積壓食品添加劑大量回收,葡萄糖">十堰庫存積壓食品添加劑大量回收,葡萄糖</a></span> </div> </div> </div> </div> </div> <div id="qwcagsgoaso" class="list"> <h2 class="titles" 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